McLane joins Citi from rival Morgan Stanley (MS.N), where he worked for 15 years, most recently as head of the financial institutions group for the Asia-Pacific region.
During that time, McLane worked on some of the region's most high-profile deals in the financial sector.
He was involved in the $22 billion IPO of Agricultural Bank of China (601288.SS) in 2010, in Singapore DBS's DBSM.I $2.8 billion rights issue, and in the $5.2 billion merger between OUB and UOB.
McLane, who will relocate to Singapore from Hong Kong when he joins Citigroup, also worked on Thanachart Capital's $2.0 billion acquisition of Siam City Bank.
(Reporting by Lawrence White; Editing by Ryan Woo)
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